Soot around boiler

[mholzap]

I noticed my boiler has been covered in soot. It looks like it’s been happening for the past couple of weeks. I recently changed my Nest to be 5 degrees colder at night instead of the same temp all day/night. I’m also noticing very loud hissing coming from the radiators, which hasn’t happened in the 6 years I’ve been in the house. Any ideas on the problem?

 

[Geofd]

When was the last time it was cleaned and serviced that should be a yearly thing, treat your boiler just like any mech thing you need to change the oil in your car periodically+ seed and cut your grass, it's just another (important) thing that requires maintenance

 

[breplum]

Ain't soot. Rusty boiler water is what I see and I ain't a hydronic guy.
from the pics, looks like an air vent pair that are fouled.
hopefully an actual pro will contribute pearls of wisdom.