heat it with a torch, it will casuse the metal to expand a little and crack any rust solidifying the joint.... DO NOT DO THIS IF IT IS A GAS LINE. also try lps Penetrant, works pretty good.
What you might be missing to remove the piping is a breaker bar ( a 2' to 3' piece of iron pipe put over the handle part of the pipe wrench). A breaker bar with the other suggestions should remove the pipe.
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